The original caption is "by Henry Walter ('H. Walter') Barnett, vintage bromide print, 1910.” This is essentially an out take from the last image of her (but without a hat) where she is called the Duchess of York. Mary was the Duchess of York from her marriage in 1893 until Queen Victoria died in 1901, at which time Mary became the Princess of Wales.
From theimperialcourt.tumblr.com/page/8; flaws removed and both lower corners fixed with Photoshop and the sepia tone was removed and the image enlaged by half.