She bore six offspring of Louis XIV. Her Wikipedia article is here. They had one daughter who survived to 18 and beyond - Marie Anne de Bourbon (1666-1739); after her father Louis XIV legitimised her, she was known as Mademoiselle de Blois. She later married Louis Armand I, Prince de Conti and, through this marriage, became officially recognised as a Princess of the Blood.
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1556 Catherine de Medici possibly by Agnolo Bronzino
1670s Gabriela Mancini by Jacob Ferdinand Voet (Hermitage)
Louise de la Valliere with her children from the king Mlle de Blois and Comte Vermandois by Pierre Mignard (Versailles)
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