She married Gaston Bourbon, brother of King Louis XIII, when France and Lorriane were at war. They married twice and then a third and final time when a dying Louis XIII forgave his brother. Her Wikipedia article is here.
Grand Ladies
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ca. 1555 Caterina de' Medici by ? (Galleria degli Uffizi - Firenze, Toscana, Italy)
Henrietta Maria after Sir Anthonis van Dyck (Bowes Museum - Barnard Castle, County Durham UK)
1634 Marguerite de Lorraine by Sir Anthonis van Dyck (Galleria degli Uffizi - Firenze, Toscana Italy)
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