While Tsar Paul I had a daughter named Elena Pavlovna, this album covers Grand Duchess Elena Pavlovna, née Charlotte of Württemberg who married Grand Duke Mikhail in 1822. She lived until 1873, having lived 66 years. Her Wikipedia article is here.
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1556 Catherine de Medici possibly by Agnolo Bronzino
ca. 1830 Grand Duchess Elena Pavlovna by A. Gral (State Russian Museum, Saint Petersburg)
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