Maria Carolina was born Archduchess of Austria, daughter of Empress Maria Theresia. Her Wikipedia article is here.
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1556 Catherine de Medici possibly by Agnolo Bronzino
Maria Francisca Pignatelli and Gonzaga, Duchess of Medinaceli by Anton Raphael Mengs (location unknown to gogm)
Marie Caroline, Queen of Naples by Landini (location unknown to gogm)
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