Possibly Rosalia Ventimiglia y Moncada

There is not much available about Rosalia Ventimiglia, but her genealogical sketch is here.

From dinastias.forogratis.es/grandes-casas-ducales-espanolas-t2460-24; posted by Gorje San on 8 October 2011.

This small image shows a woman in a big cape, apparently with expansive side panels.

Keywords:  Rosalia Ventimiglia, Duchess of Alba, Ventimiglia family, Fitz-James Stuart y Silva family, Duchess, Spanish, straight coiffure, hat, strap, bows, high neckline, cape, crinoline

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