I can find very little about her. Based strictly on lifespan dates, this is María Pilar Osorio y Gutierrez de los Rios, 3ª duquesa de Fernán Nuñez.
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1556 Catherine de Medici possibly by Agnolo Bronzino
1855 María Dolores de Aldama y Alfonso, marquesa de Montelo by Federico Madrazo y Kunz (Prado)
Duquesa de Fenán Núñez dressed for a costume ball
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