Élisabeth de France, born in 1602, was married to Felipe IV at the same time that her brother Louis (Louis XIII) was married to Anne of Austria/Spain - the seal on a mutual security pact between the Habsburgs and Bourbons. She was Queen from 1621 until she died in 1644. Her Wikipedia article is here.
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1556 Catherine de Medici possibly by Agnolo Bronzino
1665 Margarita de Austria by Diego Rodríguez de Silva y Velázquez and Juan Bautista Martínez del Mazo (Prado)
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