Her Wikipedia article is here. She was a direct descendant of Hortense Mancini and she bore her first husband, Prince Honoré IV of Monaco, two sons who both had a chance to rule Monaco. She also bore two illegitimate daughters. Their marriage ended in divorce in 1798. She was a Duchess suo jure.
This is probably excerpted from the next image that lists the artist and location.
From the lost gallery's photostream on flickr.