From antique-royals.tumblr.com; sepia tone removed.
Marie Valerie appears to be wearing a pouter pigeon rather than a wasp-waisted bodice, suggesting later 1890s.
Keywords: Archduchess Marie Valerie, Marie Valerie Mathilde Amalie, Habsburg family, Archduchess, frizzy coiffure, lace under-bodice, high enclosing neckline, pin, over-bodice, square neckline, bertha, long close leg-o-mutton sleeves, waist band, bows, close skirt